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PVC (Polyvinyl Chloride - recycling number 3) uses poisonous Chlorine for manufacturing and releases carcinogenic dioxin when manufactured or incinerated. Soft PVC plastic contains "plasticizers" (the most widely-used being phtalates) that can offgas and are linked to hormone disruption. These are the reasons for not using PVC bottles. PVC bottles are transforming a green product into its evil opposite.
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